Chiral Bioinspired Plasmonics: A Paradigm Shift for Optical Activity and Photochemistry
نویسندگان
چکیده
This Perspective concerns the latest developments in field of chiral nanocrystals (NCs) and metastructures, focusing primarily on plasmonic nanostructures. Such nanomaterials exhibit unusually strong near-field electromagnetic responses that enable efficient biosensing light manipulation. Herein we share our thoughts trends mark what call a paradigm shift for vast dynamic chiroptical materials. The topics to be considered include polarization-sensitive photocatalysis with NCs, bioconjugates, DNA-based assemblies, growth, also describe fundamental challenges optical induction chirality, transfer chirality between different scales, theoretical issues nanoscience is facing.
منابع مشابه
A Methodology for Paradigm Shift to Explain Sustainable University
The sustainable university concept is rooted in prevalent paradigms pertained to economic, social and environmental development, which all focus on systemic thought and rationality; besides, they tend to discover and solve problems by applying an interdisciplinary approach. However, the epistemic component is what these paradigms have ignored. The purpose of this study is to explain a methodo...
متن کاملChiral plasmonics
We present a comprehensive overview of chirality and its optical manifestation in plasmonic nanosystems and nanostructures. We discuss top-down fabricated structures that range from solid metallic nanostructures to groupings of metallic nanoparticles arranged in three dimensions. We also present the large variety of bottom-up synthesized structures. Using DNA, peptides, or other scaffolds, comp...
متن کاملUnderstanding complex chiral plasmonics.
Chiral nanoplasmonics exhibits great potential for novel nanooptical devices due to the generation of a strong chiroptical response within nanoscale metallic structures. Recently, a number of different approaches have been utilized to create chiral nanoplasmonic structures. However, particularly for tailoring nanooptical chiral sensing devices, the understanding of the resulting chiroptical res...
متن کاملCAREER: Doped Graphene: a Transformative Paradigm for Plasmonics and
Doped graphene, a one-atom-thick but highly conductive sheet, provides us with an unprecedented platform to explore surface plasmon and two-dimensional optics in a regime that can hardly be obtained with noble metals or conventional electron gases. Theoretical calculations show that graphene surface plasmon (transverse magnetic mode) shows extraordinarily tight confinement and short wavelength....
متن کاملTheoretical study of magnetic susceptibility and optical activity of small molecules containing one chiral center
In the first part of this work, correlation between optical activity and elements of magnetic susceptibility tensor (MST) for five classes of model small molecules containing a single chiral center has been studied using quantum computational techniques at DFT-B3LYP level of theory with 6-311G basis set. Several molecular properties are used to reduce the MST elements prior to the examination o...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: ACS Photonics
سال: 2022
ISSN: ['2330-4022']
DOI: https://doi.org/10.1021/acsphotonics.2c00445